乙烯工业 ›› 2022, Vol. 34 ›› Issue (2): 34-36.

• 工业技术 • 上一篇    下一篇

乙烯装置废碱氧化汽提塔改造及运行

董万军,彭志翔,赵 轶,刘益材   

  1. 中国石油四川石化有限责任公司,四川 成都 611930
  • 收稿日期:2021-02-25 修回日期:2022-01-21 出版日期:2022-06-25 发布日期:2022-06-28
  • 作者简介:董万军,男,2010年毕业于大连理工大学化学工程专业,硕士,主要从事技术生产工作,工程师。

Revamping and Operation of Spent Caustic Stripper in Ethylene Plant

Dong Wanjun,Peng Zhixiang,Zhao Yi,Liu Yicai   

  1. PetroChina Sichuan Petrochemical Company Limited, Chengdu, Sichuan, P.C.611930
  • Received:2021-02-25 Revised:2022-01-21 Online:2022-06-25 Published:2022-06-28

摘要:

乙烯装置废碱氧化单元是重要的环保处理装置。主要以氧化的方式处理硫化物(Na2S等),在进入氧化反应工序前,一般设计汽提塔用于除去废碱液中携带的黄油等烃类,该部分烃类在高温条件下,易聚合结垢堵塞汽提塔,影响装置平稳运行。汽提塔堵塞后,常利用水力清洗的方式进行检修,产生大量的黄油聚合物等危废,处理难度较大,同时作业环境恶劣,安全环保风险较大。通过改造建立了汽提塔洗油浸泡、循环清洗流程,项目投用后可有效解决以上问题。

关键词: 乙烯装置 , 废碱汽提塔 , 堵塞  技术改造

Abstract:

The spent caustic oxidation unit of ethylene plant plays an important role in environmental protection. The unsaturated sulfide including Na2S in the spent caustic solution is mainly saturated by oxidation. Before entering the oxidation section, a stripper is generally designed to remove hydrocarbons such as the polymer of carbonyls and dienes carried in the spent caustic solution. This part of hydrocarbons is easy to polymerize at high temperature and block the stripper, affecting the smooth operation of the plant. After the stripper is blocked, it is often repaired by means of hydraulic cleaning, which produces a large amount of hazardous wastes including the polymer of carbonyls and dienes. The wastes are difficult to treat, the operating environment is harsh and the safety and environmental protection risks are high. By establishing the process of wash oil soaking and circulating cleaning in the stripper, the above-mentioned problems can be effectively solved after the project is put into operation smoothly.

Key words: ethylene plant, waste caustic stripper, blockage, technical revamping