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2024, Vol. 36,No. 4 Published:25 December 2024 |
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Joint
Optimization Design of Pygas Hydrogenation Unit and Styrene Extraction Unit
Bai Yan, Zhu Chao, Wang Wenping
2024, 36 (4):
1-5.
Pygas hydrogenation unit and styrene extraction unit
are mutually upstream and downstream, with raw materials and products supplied
to each other and close operational connections. Based on the process
optimization and system integration research on these two units, measures such
as joint separation process, thermal coupling for distillation separation, joint
hydrogenation reaction and joint utilities can be taken. After optimization,
the joint design of pygas hydrogenation unit and styrene extraction unit is
feasible in engineering and can achieve the goals of reducing the investment,
saving the energy consumption, and improving the economic benefits and
competitiveness of the units.
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Application of Cracking Raw Material Evaluation System
Song Zhiqi, Zhang Le, Xu Hongwei, Zuo Yongguang, Liu Po
2024, 36 (4):
6-10.
In recent years, a research
institute of a petrochemical company and some production plants have adopted
information-based means to establish a database system for evaluation of
cracking raw materials, which integrates the evaluation data of cracking raw
materials into the database system for scientific and effective management. By
making the classification, filing, management, transfer and analysis of data
normalized, systematic and professional and making efficient use of the evaluation
data, the database system can play a full role in raw material procurement,
mixing, processing and production scheme optimization.
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Exploration and Practices of Online Maintenance of
Process Water Stripping Towers
Zhang Lei, Xue Xinchao, Li Zhonghua, Lyu Xiaogang, Ni Yong
2024, 36 (4):
11-14.
The process water
stripping tower for the 220 kt/a ethylene plant of PetroChina Dushanzi
Petrochemical Company had problems such
as clogged packing and poor packing at the end of its operation. The operation was
optimized by adding level gauges to the process water stripping tower,
increasing the scale removal frequency of the system and injecting dispersant,
so as to solve or alleviate the blockage in the packing layer of the process
water stripping tower. Through online isolation and repair of the process water
stripping tower, the operation bottleneck of process water system was solved.
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Application of Python
Programming in Analyzing Real-time Production Data of Ethylene Plants
Huang Xinyuan
2024, 36 (4):
15-20.
After
the processing capacity of an ethylene plant in Sinopec was expanded to 1.1
million tons per year, the vacuum degree of its cracking gas compressor unit
decreased. The real-time operation parameters related to the condenser in
different time periods were exported from the real-time database, python
programming language was used to classify, screen and clean the big data of
chemical production, the correlation was analyzed through mathematical
statistics, and a three-dimensional scatter diagram was made. A multiple linear
regression model of exhaust pressure was constructed based on historical data,
and its accuracy was verified.
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Optimization
Measures for Improving Selectivity of Back-end C2 Hydrogenation
Reaction
Zhang Hu, Wang Wen, Huang Bowei, Hu Zhigang, Kenjibieke•Xiamuxi
2024, 36 (4):
27-30.
The C2 hydrogenation reactor (R-401C/D) in
the 220 kt/a ethylene plant of PetroChina Dushanzi
Petrochemical Company was put into operation on November 8, 2022, and the ethylene
increment at the reactor outlet was unstable during production. Product yield
analysis software was used to extract production data every 4 hours to optimize
the cracking depth and control the acetylene content at the reactor inlet. The
EVA process of polymer grade ethylene was used to ensure that the flow rate of
polymer grade ethylene was maintained at 26 t/h, so as to balance the cooling
capacity of the system and control the overhead temperature of the deethanizer.
The green oil in the first stage of reactor was removed regularly, and the
amount of green oil entering the second stage bed was reduced, thus improving the
activity of catalysts and the ethylene increment at the reactor outlet. In
2023, the average ethylene increment at the reactor outlet was 301 kg/h, with
an average increase of 165 kg/h compared with that in the technical agreement.
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Practice
and Effect of Chemical Cleaning of Quench Oil Tower in Ethylene Plant
Zou Jingyi, Liu Yi
2024, 36 (4):
31-35.
During
the second overhaul of the 800 kt/a ethylene plant of a petrochemical company
in Sichuan, some chemical cleaning methods were used to remove the ferrous
sulfides, heavy oil components and hydrocarbon polymers in quench oil tower
system as well as the waste alkali grease, rust and other scale deposits in alkaline
washing tower, waste alkali collection tank and waste alkali tank. After the cleaning,
the equipment met the requirements of maintenance/production, and the goal of clean
surface was achieved.
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Reasons and Countermeasures for Low Qualified
Rate of Ethylene Products
Yang Pan, Lei Xiao, Bai Zhonghui, Liang Duo, Sun Youfang
2024, 36 (4):
36-39.
In this paper, the ethylene products of an ethylene
plant are studied. The large fluctuations in the CO content of cracking gas in
a short period of time led to bed temperature runaways in C2 hydrogenation reactor, and the pulverization and carbonization of catalysts led
to a decrease in the activity of catalysts, resulting in high acetylene at the
reactor outlet and low qualified rate of ethylene products. The temperature runaway
in C2 hydrogenation reactor caused by CO fluctuations under typical
working conditions was analyzed, and strategies were formulated from two
aspects of process adjustment and catalyst replacement, so as to effectively
solve the problem.
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Cause Analysis and Solutions to Wear and
Tear of Floating Ring Seal of Propylene Refrigeration Compressor
Zhang Yanquan, Wang Yanjiang, Zeng Denglin, Yin Fei, Wang Dongsheng
2024, 36 (4):
40-43.
To solve the wear and tear problem
of the floating ring seal of propylene refrigeration
compressor, analysis is made from the aspects of installation clearance check
of floating ring seal, quality of unit seal assembly, oxidation resistance test
of seal oil, cleaning conditions of high-level oil tank for seal oil, and
pressure difference between oil and gas, and some solutions are put forward for
the wear and tear of floating ring seal.
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Cause Analysis and
Treatment of High Bearing Pad Temperature of Cracking Gas Compressors
Zhou Jiacheng
2024, 36 (4):
44-47.
During the factory acceptance test of cracking gas
compressor for a 1,200 kt/a ethylene plant, the radial bearing pad temperatures
of low-pressure and medium-pressure cylinders exceeded the performance
assessment indicators. This could be caused by the abnormal friction between
the bearing pads and the shaft or by insufficient supply of lubricating oils
which leads to poor heat dissipation. Excessively
high bearing pad temperatures can cause thermal degradation of lubricating oils,
leading to the formation of soft contaminants that deposit on the surfaces of
bearing pads and shaft, and resulting in carbonization, sludge or even varnish.
This reduces the lubricating and cooling effects of lubricating oils,
accelerates the wear of bearing pads, and severely affects the long-term
operation of cracking gas compressor. Since cracking gas compressor is one of
the key core equipment in ethylene plant, its stable operation time directly
determines whether the ethylene plant can achieve a safe, stable, long-term,
full-load and optimum operation. Therefore, a comprehensive and scientific
analysis shall be made for the causes of high bearing pad temperature, and a
treatment plan shall be developed to solve this problem, so as to meet the
mechanical trial run acceptance standards for compressors.
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Operation Bottlenecks in the Third Stage of Cracking Gas Compressor and
the Optimization Measures
Zhang Zhifei, Bai Yunfei, Dong Yalong, Sun Shuang, Liu Guangyi
2024, 36 (4):
52-56.
The cracking gas compressor in the 220 kt/a ethylene plant of PetroChina Dushanzi
Petrochemical Company was started in September 2019 after overhaul, the
third-stage outlet flow rate was maintained at around 118 t/h, and the
third-stage outlet pressure reached a maximum of 1720 kPa, which is close to
the set pressure of safety valve of 1746 kPa, resulting in limited load
adjustment of cracking gas compressor and weakened ability to resist
fluctuations. In response to the abnormal third-stage outlet pressure of
cracking gas compressor and the deviations from design conditions, the
operating process parameters and mechanical structure of the compressor were
analyzed, and some measures such as setting internal control indicators for
compressor outlet pressure, replacing inter-stage gas seals and adding
high-pressure nitrogen sealing pipelines were taken to ensure the long-term,
full-load and optimal operation of the cracking gas compressor.
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Application of Intelligent Detection Technology
for Tubes of Ethylene Crackers
Yang Chi, Xue Miao, Shi Tiantian, Xu Zhaoqing, Zhang Minghao
2024, 36 (4):
57-60.
This paper studies in
depth the carburization failure mechanism and detection principles for tubes of
ethylene cracker, and introduces an innovative intelligent carburization
detection system. This system enables rapid carburization detection and analysis
across the entire tube, significantly improving equipment management and
maintenance efficiency and enhancing the sustainability and safety of
industrial production. During the application of this system in the ethylene
cracker of a petrochemical company, the detection data clearly indicates that
the extent of carburization is influenced by various factors including both the
temperature field generated by burners and the turbulence of medium inside
furnace tubes. The 3D carburization data for each tube provides precise
guidance for tube replacement. This intelligent carburization detection system
helps reduce operational risks, optimize process parameters, implement accurate
tube replacement and improve the economic benefits of enterprises.
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Research on Modification of Installation
Mode for Feed Flow Meter of Cracking Furnace in Ethylene Plant
Wang Jieliang, She Xingjin, Hu Peng
2024, 36 (4):
61-64.
The
feed to cracking furnace of ethylene plant is generally the mixture of gaseous raw
materials and diluted steam in a certain proportion. Because the feed contains
a certain proportion of steam, the measuring medium easily condenses during the
actual measurement, resulting in phase instability of the measuring medium
which leads to large deviations or fluctuations in flow measurement. The
inaccurate measurement of cracking furnace feed flow will lead to the failure
to use automatic control for the feed to cracking furnace, so that the labor
intensity of process operators in monitoring DCS operation screen greatly
increased, which makes it impossible for them to balance the normal control of
cracking furnace, thus resulting in a short operation cycle of cracking furnace
and the frequent switching of cracking furnace and then affecting the
production efficiency of enterprises. By optimizing and improving the
installation mode for feed flow meter of cracking furnace, the stability and
accuracy of measuring instrument can be effectively guaranteed, the problem of
measurement distortion can be solved, and the monitoring and maintenance
intensity of measuring instrument personnel and technical personnel can be
reduced, so as to achieve the long period operation of cracking furnace.
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