pyrolysis gasoline;styrene;decoloring technology;maleic anhydride;technology improvement,"/> 裂解汽油苯乙烯抽提工艺技术的改进探讨

乙烯工业 ›› 2022, Vol. 34 ›› Issue (2): 4-7.

• 综述 • 上一篇    下一篇

裂解汽油苯乙烯抽提工艺技术的改进探讨

鲁卫国,付 培,周召方   

  1. 中韩(武汉)石油化工有限公司,湖北 武汉 430082
  • 收稿日期:2021-06-28 修回日期:2022-01-23 出版日期:2022-06-25 发布日期:2022-06-28
  • 作者简介:鲁卫国,男,2015年毕业于中国石油大学(北京)石油工程专业,学士,主要从事乙烯装置的工艺和生产管理工作,工程师。

Improvement of Styrene Extraction Process for Pyrolysis Gasoline

Lu Weiguo, Fu Pei, Zhou Zhaofang   

  1. SINOPEC-SK (Wuhan) Petrochemical Company Limited, Wuhan, Hubei, P.C.430082
  • Received:2021-06-28 Revised:2022-01-23 Online:2022-06-25 Published:2022-06-28

摘要:

介绍了中韩石化苯乙烯抽提装置存在的问题及其改进措施。装置首次运行仅2.5个月便发生了苯乙烯精制塔进料以下的填料严重堵塞的问题,结合实际生产运行过程的各项数据,分析了C-401塔运行周期短的原因,总结了有机酸脱色工艺的主要缺点。针对马来酸酐极易与苯乙烯发生聚合反应的缺点,从降低马来酸酐浓度、降低操作温度、用新型脱色剂替代纯马来酸酐、改造塔内件等方面进行了尝试,对比实施前后的实际运行效果,几个方面的改进取得了成效。

关键词: 裂解汽油  苯乙烯  脱色工艺 , 马来酸酐 , 技术改进

Abstract:

The problems in the styrene extraction unit at SINOPEC-SK (Wuhan) Petrochemical Company Limited and the improvement measures are introduced. Serious blockage of packing below the feed nozzle of styrene refining tower occurred only 2.5 months after the first startup of the unit. The reasons for the short operation period of the refining tower were analyzed combined with various data of the actual operation, and the main shortcomings of organic acid decoloring process were summarized. In order to overcome the disadvantage of easy polymerization of maleic anhydride with styrene, some attempts were made, such as lowering the concentration of maleic anhydride, lowering the operating temperature, replacing the pure maleic anhydride with a new decolorant and modifying the equipment. The comparison of the actual operation results before and after the implementation showed that several improvement attempts have achieved certain results.

Key words:  , pyrolysis gasoline;styrene;decoloring technology;maleic anhydride;technology improvement')">pyrolysis gasoline;styrene;decoloring technology;maleic anhydride;technology improvement