乙烯工业 ›› 2018, Vol. 30 ›› Issue (3): 6-11.

• 综述 • 上一篇    下一篇

丁烯氧化脱氢制丁二烯装置热量分析

贾崑   

  1. 中国石化工程建设有限公司,北京 100101
  • 收稿日期:2018-05-14 接受日期:2018-06-25 出版日期:2018-09-28 发布日期:2018-09-28
  • 作者简介:贾崑,男,2011年毕业于美国伊利诺伊理工大学,硕士,现从事工艺流程设计、技术开发、专利编制等工作,工程师。

Pinch Analysis of Oxidative Dehydrogenation of Butene to Butadiene Technology

Jia Kun   

  1. SINOPEC Engineering Incorporation, Beijing, P.C.100102
  • Received:2018-05-14 Accepted:2018-06-25 Online:2018-09-28 Published:2018-09-28

摘要: 丁二烯是多种产品的重要单体,用途十分广泛,市场需求量大。目前丁二烯的生产方法主要有物理分离及丁烯氧化脱氢两种方法。运用热夹点技术对丁烯氧化脱氢装置的2个主要工艺单元(脱烷烃单元、丁二烯抽提单元)进行热量分析。通过对换热网络热夹点以及热量利用率的分析与计算,提出切实可行的换热网络集成与整合建议,达到降低公用工程消耗量,提高装置效益的目的。

关键词: 丁二烯, 丁烯氧化脱氢, 夹点技术, 换热网络, 集成优化, 节能

Abstract: Butadiene is a conjugated diene used in the production of polymers and as a chemical intermediate for several specialty products. Butadiene is produced commercially by two methods, i.e. the physical separation from the steam cracking of paraffinic hydrocarbons and the oxidation dehydrogenation of butene. In this paper, thermal pinch technology is used to analyze the two main process units (dealkylation unit and butadiene extraction unit) of the butene oxidative dehydrogenation unit. Based on the analysis and calculation of the thermal pinch point and heat utilization rate of the heat exchange network, some feasible proposals are put forward for the integration of heat exchange network, which can reduce the utility consumption and improve the efficiency of the unit.

Key words: butadiene, oxidative dehydrogenation of butene, pinch point technology, heat exchange network, integration optimization, energy saving