乙烯,NOx  ,SCR  ,液氨  ,氨水  ,尿素 ," /> 乙烯,NOx  ,SCR  ,液氨  ,氨水  ,尿素 ,"/> ethylene, NOX, SCR, liquid ammonia, ammonia water, urea ,"/> <p class="MsoNormal" align="left" style="text-align:left;"> <b>裂解炉</b><b>SCR</b><b>制氨工艺分析</b><b></b>

乙烯工业 ›› 2022, Vol. 34 ›› Issue (1): 59-64.

• 裂解炉 • 上一篇    

裂解炉SCR制氨工艺分析

曾招朋,郭克伦,路聿轩,林  畅,孙金英,贾保印   

  1. 中国寰球工程有限公司北京分公司,北京 100012
  • 收稿日期:2021-03-08 修回日期:2021-10-08 出版日期:2022-03-25 发布日期:2022-03-28
  • 作者简介:曾招朋,男,2014年毕业于中国石油大学(北京)化学工艺专业,主要从事裂解炉和LNG接收站的设计工作,已发表论文6篇,工程师。

Analysis on SCR Ammonia Preparation Processes for Ethylene Cracking Furnace

Zeng Zhaopeng, Guo Kelun, Lu Yuxuan, Lin Chang, Sun Jinying, Jia Baoyin.   

  1. China Huanqiu Contracting & Engineering Co., Ltd. Beijing Huanqiu Corporation, Beijing, P.C.100012

  • Received:2021-03-08 Revised:2021-10-08 Online:2022-03-25 Published:2022-03-28

摘要:

介绍了液氨/氨水汽化法、尿素水解法、尿素热解法、氨水直喷法、尿素直喷法等常用的SCR制氨工艺流程。结合裂解炉装置自身特点,从安全与环境风险、氨气转化率、系统响应性、综合成本等多方面进行分析比较,所有制氨工艺均不会提高乙烯装置的安全与环境风险级别,而液氨汽化法在系统响应和经济成本等方面均具有显著优势,从而得出液氨汽化法是裂解炉SCR的最佳制氨工艺。

关键词:

乙烯')">"> 乙烯, NOx  , SCR  , 液氨  , 氨水  , 尿素

Abstract:

This paper introduces five SCR ammonia preparation processes, i.e., liquid ammonia / ammonia water vaporization, urea hydrolysis, urea pyrolysis, ammonia direct injection and urea direct injection. Based on the characteristics of ethylene cracking furnace, these processes are analyzed and compared from the aspects of safety and environmental risk, ammonia conversion rate, system responsiveness and comprehensive cost. None of these ammonia preparation processes can improve the safety and environmental risk level of ethylene plant. Liquid ammonia vaporization method has the best system responsiveness and the lowest economic cost. It is concluded that liquid ammonia vaporization is the preferred SCR ammonia preparation process for ethylene cracking furnace.

Key words: ethylene')">

ethylene, NOX, SCR, liquid ammonia, ammonia water, urea