乙烯工业 ›› 2024, Vol. 36 ›› Issue (2): 11-14.

• 工业技术 • 上一篇    下一篇

石脑油脱砷系统隐患治理改造及运行

赵祥龙,周洪波,李  响,孟  飞,赵晶晶   

  1. 中国石油天然气股份有限公司独山子石化分公司,新疆 独山子  833699
  • 收稿日期:2023-02-28 修回日期:2023-07-13 出版日期:2024-06-25 发布日期:2024-06-26
  • 作者简介:赵祥龙,男,2017年毕业于中国石油大学(华东)油气储运专业,主要从事罐区、装卸区技术管理工作,工程师。

Operation of Arsenic Removal System for Naphtha after Modification for Hidden Danger Treatment

Zhao Xianglong, Zhou Hongbo, Li Xiang, Meng Fei, Zhao Jingjing   

  1. PetroChina Dushanzi Petrochemical Company, Dushanzi, Xinjiang, P.C.833699

  • Received:2023-02-28 Revised:2023-07-13 Online:2024-06-25 Published:2024-06-26

摘要: 独山子石化公司提高了玛湖原油加工比例,因该原油中砷含量较高,导致产出的石脑油砷含量超标,造成乙烯装置碳二、碳三、汽油加氢反应器催化剂中毒、催化剂寿命缩短、加氢产品质量超差等风险。目前脱砷系统存在不合规问题及运行安全风险,不具备投用条件,需对现有脱砷流程及环保不合规问题进行局部改造,脱砷系统改造投用后,系统运行合规,同时达到了良好的脱砷效果。

关键词: 石脑油  , 砷含量  , 催化剂中毒  , 产品质量

Abstract:

PetroChina Dushanzi Petrochemical Company has increased the processing proportion of Mahu crude oil. Due to the high arsenic content of Mahu crude oil, the arsenic content of the naphtha produced exceeded the standard, leading to risks such as the poisoning of catalysts for and gasoline hydrogenation reactors in the ethylene plant, the shortening of catalyst life and the poor quality of hydrogenation products. The arsenic removal system was not allowed to be put into use because there were some non-compliance problems and operational safety risks, so local modification was required for the existing arsenic removal process and the environmental non-compliance. After the modified arsenic removal system was put into use, it was operated in compliance with relevant standards, and good arsenic removal effect was achieved.

Key words: naphtha, arsenic content, catalyst poisoning, product quality