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2020, Vol. 32,No. 2 Published:25 June 2020 Previous   
OVERVIEW

Comparison and Selection of Schemes for Light Hydrocarbon Cracking to Ethylene Project of Different Scales

Li Jinfeng
2020, 32 (2):  1-6. 
Abstract ( 207 )  

With the advantages of short process flow and less investment, the cracking unit which takes light hydrocarbon as the raw material provides a new way for the revamping and expansion of ethylene plant by petrochemical enterprises. Taking a light hydrocarbon cracking project planned and constructed by an enterprise as an example, this paper puts forward three categories and six different construction schemes for comparison and selection based on the supporting conditions and development strategy, uses PIMS process planning platform system to calculate the material balance of the schemes, discusses the engineering schemes for process units and utilities, analyzes the investment and benefits of different schemes, and draws preliminary research conclusions and suggestions.

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Feasibility of Hydrogen Recovery for Ethane Cracking Plant
Wang Zhouhu
2020, 32 (2):  7-9. 
Abstract ( 209 )  

Through the comparison of yield characteristics of ethylene plant with different raw materials, the particularity of ethane cracking is shown. Based on a 1000 KTA ethane cracking plant and the assumed prices of natural gas, ethane and electricity, the hydrogen recovery cost of ethane cracking plant is obtained. If natural gas is used as the substitute heat for hydrogen, the hydrogen recovery cost depends on the price of natural gas. In regions where the natural gas price is high, the hydrogen recovery cost is relatively high and the market competitiveness is weak. If ethane is used as the substitute heat for hydrogen, when the ethane price is low, the hydrogen recovery cost of ethane cracking is close to that of coal to hydrogen, showing strong market competitiveness.

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INDUSTRIAL TECHNOLOGY
Research on Solving the Problem of Ternary Refrigeration System Using LPG Cold Energy
Chen Jing
2020, 32 (2):  10-13. 
Abstract ( 192 )  
This article analyzes the problem of over high outlet pressure at the end section of compressor in the ternary refrigeration system of an ethylene plant. Combining with the trend of lighter feedstock, a new method for reducing the pressure of the ternary refrigeration compressor using LPG cold energy is proposed. The existing LPG raw material preheating system is replaced with the newly installed LPG cold energy reconditioning system. While preheating LPG raw material , this part of cold energy is recovered by the ternary refrigeration system to alleviate the problem of over high outlet pressure at the end section of compressor in ternary refrigeration system.
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Application of Mixed Xylene in Startup of Styrene Extraction Unit
Zhou Zhaofang, Hu Junwu, Liu Liang, Tian Longsheng
2020, 32 (2):  14-15. 
Abstract ( 144 )  
The traditional startup method of styrene extraction unit is generally divided into reverse startup and sequential startup. The reverse startup is to prepare styrene products in advance and fill them into the system. The sequential startup is to start up the unit with C8/C9 raw materials according to the sequence of the process. This paper introduces the third startup method for styrene extraction unit, i.e., firstly filling mixed xylene into C8/C9 cutting tower for oil flushing, then sending the mixed xylene to extraction system after the hot flushing with solvent, and finally sending the mixed xylene to decolorization and refining system to get through the entire process for oil flushing. After the oil flushing with mixed xylene, the frequency of filter cleaning during normal feeding process is greatly reduced, and the risk of styrene polymerization caused by equipment failure during startup is reduced.At the same time, the process parameters have been optimized to the best state during the oil flushing with mixed xylene, providing favorable conditions for the production of qualified styrene products.

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Influence of Process Conditions on Thiophene Removal Reaction of Pyrolysis Gasoline by Hydrogenation
Dong Wanjun, Shi Yunwei, Zhao Weiqi, Wang Shengwei
2020, 32 (2):  16-18. 
Abstract ( 161 )  

Petroleum benzene is one of the important basic chemicals, and its industrial production process is realized in aromatics extraction unit. Most of its raw materials come from pyrolysis gasoline hydrogenation unit, accounting for more than 50% of petroleum benzene products. With the rapid development of the chemical industry, the requirements for sulfur content of benzene products in chemical market become higher and higher. Sulfur exists in benzene products mainly in the form of thiophene, and the thiophene content of products can be approximately characterized by total sulfur content. Because the physical properties of thiophene and benzene are similar, it is difficult to separate them by distillation in industrial production, and hydrodesulfurization is mostly adopted. By analyzing the chemical reaction process of thiophene removal of pyrolysis gasoline by hydrogenation and comparing the total sulfur content of hydrogenated gasoline products under different process conditions, the optimal operating conditions that can meet the sulfur content of products with the existing technologies and process conditions are obtained.

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Cause Analysis and Treatment of High Oil Content of Process Water
Yu Zhenqing
2020, 32 (2):  19-23. 
Abstract ( 216 )  

This paper analyzes and finds out the reasons for the problems of process water system in the ethylene plant at SINOPEC Tianjin Company, including the decrease in overhead stripping steam in process water stripper, the drop in overhead temperature and the over high oil content of process water. The boiler in the process water stripper is treated to increase the overhead temperature, reduce the oil content of process water, avoid the pollution of sewage system, reduce the low-pressure steam makeup, reduce the energy consumption of ethylene plant, and reduce the blowdown of dilution steam.

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Analysis of Abnormal Operation of Pyrolysis Gas Dryer and the Countermeasures
Zhang Chenglong, Zhou Jiacheng, Liang Duo, Liu Po, Xu Hongwei, Wang Zhengying
2020, 32 (2):  24-28. 
Abstract ( 165 )  

This paper introduces the abnormal operation of pyrolysis gas dryer in the 1000 kt/a ethylene plant at PetroChina Dushanzi Petrochemical Company caused by the decrease in adsorption and dehydration performance after the agent was re-screened and re-filled for the bed leakage in 2016. The reasons for the abnormal operation of pyrolysis gas dryer is analyzed, and some corresponding measures are taken to ensure the stable, safe and long-term operation of the ethylene plant under high load.

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Optimization of Emptying Plan for Overhaul of Quench System in Ethylene Plant
Chen Chen
2020, 32 (2):  29-33. 
Abstract ( 158 )  

The emptying of quench system during the overhaul of ethylene plant has always been the difficulty and control point of plant shutdown. After two rounds of revamping and expansion, there were many changes on the site of the ethylene plant of SINOPEC Qilu Company, bringing a lot of difficulties to the emptying of quench system. In view of the characteristics of quench system including a large number of equipment, complex process and heavy oil products, related processes were prepared in advance, all the disciplines coordinated with each other, and the emptying replacement speed and quality of the system were improved through scheme optimization. On the premise of recovering oil products from oily sewage as far as possible, the low-emission emptying replacement of quench system were achieved in 8 days.

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CRACKING FURNACE
Simulation of Industrial Decoking Process for Ethylene Cracking Furnace
Zhi Maoxuan
2020, 32 (2):  34-37. 
Abstract ( 208 )  
Steam-air decoking process on the inner surface of cracking furnace tube is a dynamic process with the variation of temperature, pressure, concentration and coke layer thickness along the reactor length. Assuming that the kinetic parameters and reaction heat of the decoking reaction along furnace tube remain unchanged, the mechanism model of steam-air decoking process was established based on the analysis of steam-air decoking mechanism. According to the actual decoking operation of the cracking furnace BA104 at SINOPEC Zhenhai Refining & Chemical Company, the first principle model was derived and solved with finite element analysis method. The comparison of industrial simulation results with actual production verified the feasibility and effectiveness of the derived steam-air decoking model, laying foundation for the closed-loop optimal control of decoking process.
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Discussion on Operation Cycle and Energy Saving of Heavy Oil Cracking Furnace
Jiang Mingjing
2020, 32 (2):  38-40. 
Abstract ( 181 )  

The operation cycle of the heavy oil cracking furnace at SINOPEC Zhenhai Refining & Chemical Company has reached more than 120 days, but at the end of the operation, the fuel consumption increases, the output of ultra-high pressure steam decreases and the energy consumption increases under the same feeding quantity. The energy consumption required for coke burning of cracking furnace is calculated, the ratio of feed to fuel and the ratio of ultra-high pressure steam output to fuel consumption during the whole operation cycle are analyzed, and the average data every 10 days of the 50 days before operation and that of the 50 days after operation are compared. The results show that the objectives of planned decoking and lower total energy consumption of the ethylene plant can be achieved through reasonable arrangement of operation cycle.

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Cause analysis and Countermeasures for Blockage of Anti-scorching Steam Line of Transfer Line Valve
Yang Fan, Yang Ke, Ma Cheng, You Xiaohui, Zhang Pinglin
2020, 32 (2):  41-43. 
Abstract ( 176 )  

 The structure characteristics and working principle of transfer line valve in the cracking furnace of the 220 kt/a ethylene plant at PetroChina Dushanzi Petrochemical Company are analyzed. The effect of anti-scorching steam on transfer line valve and the causes of the blockage of anti-scorching steam line are analyzed. By taking a series of measures including installing flanges downstream the steam line valve and upstream the injection point hand valve, installing heat tracing for steam lines and strengthening daily maintenance, the hidden danger of anti-scorching steam line blockage of transfer line valve was successfully eliminated.

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COMPRESSOR
Cause Analysis and Treatment of Abnormal Increase in Intake and Extraction Flow of Steam Turbine
Chi Haiqing, Wang Qingjun, Liu Xiaohui, Li Dan
2020, 32 (2):  44-46. 
Abstract ( 481 )  
After the overhaul of an extraction condensing steam turbine, the opening of intake control valve increased abnormally and the volume of extraction steam increased obviously. Through test and maintenance, it was found that the leakage of extraction check valve and the entrance of the steam from extraction pipe network into the turbine increased the pressure at the extraction nozzle, reduced the efficiency of steam turbine and caused the abnormal intake and extraction flow. The extraction check valve and its actuator were repaired, and the initial position of the check valve stem was adjusted, then the steam turbine returned to normal operation.
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Inspection and Elimination of Internal leakage in Condenser of Extraction Condensing Steam Turbine
Guo Hang, Wang Jindong
2020, 32 (2):  47-50. 
Abstract ( 169 )  

Condenser is the core equipment of condensate system of extraction condensing steam turbine. The condensate system is under negative pressure during normal operation, and the change of working state of condenser directly affects the working efficiency of steam turbine. In this paper, the on-line cleaning and leakage elimination process of the condenser in steam turbine of cracking gas compressor in the 200 kt/a ethylene plant at SINOPEC Tianjin Company is introduced, and some improvement suggestions are put forward for on-line monitoring and other deficiencies.

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Cause Analysis and Treatment Measures for Temperature Rise of Bearing Shell of Cracking Gas Compressor
Hu Hengwei, Xue Xinchao, Wang Chenyu, You Xiaohui, Zhang Mingcan
2020, 32 (2):  51-56. 
Abstract ( 190 )  
After 3 years’ operation of the cracking gas compressor in the 220 kt/a ethylene plant at PetroChina Dushanzi Petrochemical Company, the bearing shell temperature of the thrust bearings TE12820/21 in high pressure cylinder reached 120℃/121℃ (120℃ is the alarm value) and approached 125℃, which is the interlock value of compressor. The causes of this phenomenon were analyzed, and the severe coking of the impeller and flow channel of cracking gas compressor was identified as the main reason for the temperature rise of bearing shell. Some measures including adjusting the lube oil temperature, increasing the water injection rate, adjusting the injection rate of additives and installing lube oil filtration system were taken, and good effect were achieved. The bearing shell temperature of TE12820/21 dropped from 120℃/121℃ to 113℃/110℃, ensuring the smooth operation of cracking gas compressor, avoiding the unplanned shutdown of the ethylene plant and even the shutdown of the whole plant as a result of abnormal bearing shell temperature, and remarkably reducing losses.
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Solution and Optimization of Problems in Overhaul of Cracking Gas Compressor in Ethylene Plant
Liu Zehan, Su Weiyi, Pan Yanjun, Gu Yang, Hong Kun
2020, 32 (2):  57-59. 
Abstract ( 142 )  
Cracking gas compressor is the core equipment of ethylene plant, and the stable operation of the compressor unit is crucial to the continuous and safe operation of ethylene plant. This paper focuses on the overhaul items of cracking gas compressor and turbine in the 1000 kt/a ethylene plant at PetroChina Dushanzi Petrochemical Company and the problems emerged during overhaul, analyzes the causes of the problems based on process operation data, and puts forward some overhaul control measures and problem solving measures.
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OPTIMIZATION AND CONTROL
Application of APC System in Propylene Distillation Column
Gu Hongxing, Chen Wenli, Yang Guangwei, Wang Zhengying, Du Xinming
2020, 32 (2):  60-64. 
Abstract ( 218 )  
Propylene distillation column is an important product separation unit for ethylene plant. The original automatic control mode of propylene distillation column could not satisfy the requirements of stable operation of the unit under high load, and there was a great propylene loss at the bottom of the column. Through the application of advanced process control (APC) technology, the operation of propylene distillation tower was adjusted and optimized, the propylene loss in the tower kettle was reduced, the fluctuation in pressure, liquid level, flow rate, sensitive plate temperature and propylene content in tower kettle of the tower system was minimized, and the system could be operated rapidly in the optimal operation area, thus meeting the requirements of stable operation, high efficiency, energy saving, consumption reduction and efficiency improvement under high load.
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Information
Supervisor: China petrochemical corporation
Sponsor: China petrochemical engineering construction co. LTD
Address: 21 anhuili anyuan, chaoyang district, Beijing
Tel:010-84876209;84878482
E-mail:yxgy.sei@sinopec.com
ISSN:1671-7120
CN: 11-4819/TQ