乙烯工业 ›› 2018, Vol. 30 ›› Issue (4): 4-6.

• 综述 • 上一篇    下一篇

丁烷裂解性能研究

张永刚,杜志国,张利军,李蔚   

  1. 中国石油化工股份有限公司北京化工研究院,北京 100013
  • 收稿日期:2017-12-05 接受日期:2017-07-23 出版日期:2018-12-25 发布日期:2018-12-30
  • 作者简介:张永刚,男,2010年毕业于北京化工研究院化学工艺专业,硕士,主要从事乙烯裂解工艺开发工作,高级工程师。

STUDY ON PYROLYSIS PERFORMANCE OF BUTANE[4]

Zhang Yonggang,Du Zhiguo,Zhang Lijun,Li Wei   

  1. SINOPEC Beijing Research Institute of Chemical Industry,Beijing,P.C.100013
  • Received:2017-12-05 Accepted:2017-07-23 Online:2018-12-25 Published:2018-12-30

摘要: 近年来,随着我国燃料油标准的提高以及炼油装置的升级改造,原用作裂解原料的石脑油大多用作重整原料,导致裂解原料供应不足,另外丁二烯尾气全加氢技术的开展,使用丁烷用作裂解原料的几率逐渐增加。丁烷主要组成为正丁烷和异丁烷。由多种含量异丁烷的丁烷蒸汽裂解试验数据可知,正丁烷和异丁烷共裂解时存在负面效益,异丁烷含量越高将导致裂解产物中的乙烯、双烯和三烯收率降低。因此,对于用作裂解原料的丁烷,应该尽量降低其中异丁烷的含量,以提高丁烷中的乙烯、双烯和三烯收率。

关键词: 丁烷, 裂解, 三烯, 收率

Abstract: In recent years, with the improvement of China's fuel oil standards and the upgrading of refining units, naphtha, which was formerly used as raw materials for ethylene plant, are mostly used as reforming feedstock, leading to the inadequate supply of ethylene raw materials. And the hydrogenation of butadiene tail gas has gradually increased the probability of using butane as ethylene feedstock. Butane is mainly composed of n-butane and isobutane. The experimental data of butane pyrolysis shows that there is a negative benefit in the co cracking of n-butane and isobutane. The higher the isobutane content, the lower the yield of ethylene, the yields of ethylene and propylene and the yields of ethylene, propylene and butadiene are. Therefore, the isobutane content of butane, which is used as ethylene feedstock, should be reduced as much as possible to improve the yield of ethylene, the yields of ethylene and propylene and the yields of ethylene, propylene and butadiene in butane.

Key words: Ethylene, Diene, Triene, Cracking, Yield