乙烯工业 ›› 2025, Vol. 37 ›› Issue (3): 25-29.

• 工业技术 • 上一篇    下一篇

三苯芳烃抽提技术在乙烯裂解装置的应用

吕洪涛,梁  铎,王建辉,陈  名   

  1. 万华化学集团股份有限公司,山东 烟台 264000
  • 收稿日期:2024-02-28 修回日期:2025-03-15 出版日期:2025-09-25 发布日期:2025-09-28
  • 作者简介:吕洪涛,男,2014年毕业于烟台大学化学化工学院化学工程专业,硕士研究生,现从事乙烯装置工艺生产管理工作,工艺主任工程师。

Application of BTX Aromatics Extraction Technology in Ethylene Crackers

Lyu Hongtao, Liang Duo, Wang Jianhui, Chen Ming   

  1. Wanhua Chemical Group Co., Ltd., Yantai, Shandong, P.C.264000
  • Received:2024-02-28 Revised:2025-03-15 Online:2025-09-25 Published:2025-09-28

摘要:

乙烯裂解装置生产的裂解汽油,经过预分馏脱除C5及以下和C9以上组分后,再经两段加氢将烯烃加氢为饱和烃,并脱除硫、氮、氧等杂质得到裂解加氢汽油,以此为原料经三苯芳烃抽提和精馏分离后,得到苯(B)、甲苯(T)、混合二甲苯(X)等产品。文中分析了以裂解加氢汽油为原料的三苯芳烃抽提装置的工艺路线以及装置操作的要点;与传统芳烃抽提的不同点是引入了抽余油萃取系统和水洗耦合工艺,用以回收非芳烃中的苯并去除非芳烃中的溶剂,解决了三苯芳烃抽提中C8非芳烃和芳烃分离的技术难题,同时通过耦合工艺解决了重组分累积导致溶剂品质恶化的问题;将芳烃精馏系统甲苯(T)、混合二甲苯(X)、重质芳烃的分离双塔集成为单塔,得到合格的甲苯(T)和混合二甲苯(X)产品。

关键词: 裂解加氢汽油 , 芳烃抽提 , 三苯抽提蒸馏

Abstract:

Pyrolysis gasoline from ethylene cracker undergoes pre-fractionation to remove C5 and lighter components and C9+ components, and then undergoes two-stage hydrogenation to hydrogenate olefins into saturated hydrocarbons and remove impurities such as sulfur, nitrogen and oxygen to obtain hydrogenated pyrolysis gasoline. The hydrogenated pyrolysis gasoline is separated by BTX extraction and distillation to obtain products such as benzene, toluene and mixed xylene. In this paper, the technological route and operation key points of BTX aromatics extraction unit with hydrogenated pyrolysis gasoline as the feed are analyzed. It differs from the traditional aromatics extraction in the introduction of raffinate extraction system and water washing coupling process, which recovers benzene from non-aromatic hydrocarbons and removes solvents from non-aromatic hydrocarbons. The technical problem of separating C8 non-aromatics from aromatics in BTX extraction can be solved, and the solvent quality deterioration caused by the accumulation of heavy components can be solved by the coupling process. The two separation columns of toluene, mixed xylene and heavy aromatics in the aromatics distillation system are integrated into a single column to obtain on-spec toluene and mixed xylene products.

Key words: hydrogenated pyrolysis gasoline, aromatics extraction, BTX extractive distillation