Ethylene Industry ›› 2023, Vol. 35 ›› Issue (2): 29-32.

• INDUSTRIAL TECHNOLOGY • Previous Articles     Next Articles

Cause Analysis and Countermeasures for Excessive CO in Cracking Gas

Liu Chi1, Wu Chuanpeng2, Tan Weihong1, Zheng Wenjing1, Gou Chengdong2   

  1. 1. ZhongKe (Guangdong) Refinery & Petrochemical Company Limited, Zhanjiang, Guangdong, P.C.524000; 2. SINOPEC Research Institute of Safety Engineering Co., Ltd., Qingdao, Shandong, P.C.266100
  • Received:2022-09-09 Revised:2023-02-14 Online:2023-06-25 Published:2023-07-11

Abstract:

Ethylene is an important basic raw material for petrochemical industry, and CO will be generated during ethylene cracking. Excessive CO in cracking gas will lead to the poisoning of C2 hydrogenation catalyst and the leakage of acetylene, resulting in unqualified ethylene products or even the interlock shutdown of the plant and affecting normal ethylene production. This paper discusses the generation process of CO in steam cracking unit, and systematically analyzes the causes of the excessive CO in cracking gas according to the actual production conditions of the plant. The main reasons for the excessive CO in cracking gas are the over high COT in cracking furnace, the reduced sulfur content of cracking raw material and the incomplete passivation of furnace tube before feeding. Some corresponding countermeasures are proposed according to the reasons for the excessive CO.

Key words: ethylene cracking, excessive CO, coil outlet temperature/COT, sulfur content