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2020, Vol. 32,No. 3 Published:25 September 2020 Previous   
OVERVIEW
Influence of Gradual Replacement of Naphtha with Ethane on Ethylene Plant
Zhao Bairen, Wang Zhenwei, Sheng Zaihang
2020, 32 (3):  1-6. 
Abstract ( 298 )  
In an ethylene plant where naphtha is used as the feedstock, naphtha is gradually replaced with ethane while maintaining the ethylene production unchanged. The analysis on the overall material balance of feedstock, products and by-products shows that only the yields of a few components such as hydrogen and recycle ethane increase while the other components, feedstock and cracked gas decrease. The modification direction of ethane preheating exchanger and cracking furnace is pointed out, and the bottleneck of ethylene recovery is predicted. Through statistical comparison of process simulation results, the trends of fuel, steam, cooling water, power and energy consumption are summarized.
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Optimization of Emission Reduction Scheme for Startup and Shutdown of Ethylene Plant
Fan Shiping
2020, 32 (3):  7-12. 
Abstract ( 235 )  
With the continuous improvement of national environmental protection standards, enterprises achieve the emission reduction and up-to-standard discharge of the three wastes by optimizing the start-up and shutdown scheme and effectively balancing the startup and shutdown schedule. For ethylene plant with complex process flow, it is especially important to achieve environmental-friendly, economical and high-efficiency startup and shutdown. Following the principle of environmental protection priority, the ethylene plant of Shanghai SECCO strictly controls the discharge of the three wastes during startup and shutdown, takes economy and high-efficiency as the goal, maximizes the recovery of hydrocarbons, and balances the environmental protection and economy during startup and shutdown by means of schedule control. Good results have been achieved.
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INDUSTRIAL TECHNOLOGY
Problems in Deethanizer System and the Optimization
Huang Dengsheng, Shi Changhong, Ma Jun, Jiang XIaoyong
2020, 32 (3):  13-15. 
Abstract ( 296 )  

In view of the high propylene content of overhead stream and the over high ethane in tower bottoms of deethanizer in the No.2 ethylene plant in Dushanzi, this paper analyzes the design data and operation data of deethanizer feed, tower bottom product and front-end predistillation system, and concludes that the high temperature of feed in the No.2 predistillation tower is the cause of the high overhead temperature and high propylene loss of deethanizer. Through technical transformation, by-pass regulation is installed, the quantity and temperature of the feed to deethanizer are reduced, the distillation effect of deethanizer is improved, and the loss of overhead C3 and the loss of C2 in tower bottoms are reduced.

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Analysis on Optimization of Ethylene Plant for Energy Saving and Emission Reduction
Li Zhiyuan, Ma Jun, Shang Yongfu, Ding Lu, Ma Lifan
2020, 32 (3):  16-18. 
Abstract ( 260 )  

Through the analysis on the material balance, steam/water balance and environmental pollution data in the No.2 Workshop of the Ethylene Plant in Dushanzi, it is concluded that the causes of high material consumption, high energy consumption and high pollution of ethylene plant include the high temperature emission of flue gas from cracking furnace, the coking gas from coke oven, the discharge of breathing valves in doom roof tank area, and the discharge of water system, oil system and caustic system. Corresponding measures are taken to prevent and reduce the production of pollutants.

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Effect of Lighter Feedstock on Cracking Gas Compressor and the Optimization Measures
Wang Chenyu, Dong Yalong, Ren Chongxin, Ma Jun, You Xiaohui
2020, 32 (3):  19-21. 
Abstract ( 256 )  

As the feedstock to the 220 kt/a ethylene plant at PetroChina Dushanzi Petrochemical Company becomes lighter, the cracking gas components becomes lighter, and some problems such as high suction pressure and low discharge pressure gradually emerged in the cracking gas compressor. As a result, the ethylene yield and the output cannot meet the requirements at the same time. This paper introduces the analysis and investigation process of the influence of lighter cracking gas components on cracking gas compressor, and puts forward some optimization measures and suggestions.

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CRACKING FURNACE
Problems in Long-Term Operation of Cracking Furnace and the Optimization Measures
Jiang Pengfei, Su Weiyi, Luo Lingli, Gu Yang, Hong Kun
2020, 32 (3):  22-28. 
Abstract ( 271 )  
This paper focuses on the bottlenecks in the long-term operation of cracking furnace in the 1000 kt/a ethylene plant at PetroChina Dushanzi Petrochemical Company, analyzes the causes of the problems, and takes reasonable measures to solve the problems including the frequent leakage of primary steam injection line, the blockage of furnace tube in the radiant section of cracking furnace, the leakage of furnace tube in convection section, the leakage of boiler feed water regulating valve, the leakage of steam drum connecting elbow, the vibration shift of zirconia and the blockage of light hydrocarbon regulating valve cage. The operating cycle of cracking furnace was improved, and the economic benefit of the enterprise was increased.
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Application of SCR Denitration Technology in Ethylene Cracking Furnace
Dai Bing, Wang Ping, Wang Xiaorui, Yang Xue
2020, 32 (3):  29-34. 
Abstract ( 262 )  
In recent years, with the gradual improvement of environmental awareness and the implementation of the new version of Environmental Protection Law in China, the pollutant emission indicators for petrochemical enterprises have become increasingly stricter. In order to reduce the content of nitrogen oxides (NOx) in cracking furnace flue gas, domestic ethylene plants currently use low nitrogen burner technology to control the amount of NOx in the flue gas. As the environmental protection requirements become more stringent, it is necessary to meet the lower NOx emission target of cracking furnace flue gas. This paper briefly introduces the application of SCR denitration technology in the cracking furnace of a newly-built ethylene plant, specifically describes the SCR technology in the operation of cracking furnace, and puts forward some suggestions for optimization and improvement.
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Structural Design of Header Box in Ethylene Cracking Furnace
Lu Dan
2020, 32 (3):  35-38. 
Abstract ( 166 )  
The structural design of header box is an essential part in the design of the convection section of ethylene cracking furnace. It directly affects the safe operation and heat loss of cracking furnace, and greatly influences the convenience of disassembly and assembly during maintenance and repair and the repair difficulty of damaged structures. This article analyzes and compares the selection and performance of lining materials as well as the structural design and construction of various linings and their composite forms in the structural design of header box in cracking furnace, so as to achieve optimized design.
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Energy Saving Analysis of Mechanical Coke Cleaning and Chemical Cleaning for Cracking Furnace
Ren Chongxin, Ye Minglu, Wang Xiwang, Dong Zhiquan, Kang Hongcai
2020, 32 (3):  39-41. 
Abstract ( 270 )  
During the long period operation of ethylene cracking furnace, ash deposited on the surface of furnace tube and coke formed inside the furnace tube in convection section, resulting in higher flue gas temperature of cracking furnace, lower heat transfer efficiency of furnace tube in convection section, and higher heat loss and energy consumption and lower thermal efficiency of cracking furnace. To solve these problems, a combination of mechanical coke cleaning and chemical cleaning was adopted to remove the ash on the surface of furnace tube and the coking inside the furnace tube in the convection section of cracking furnace, so as to improve the thermal conductivity of tube bundle in convection section, improve heat transfer efficiency, and achieve the desired flue gas temperature and thermal efficiency.
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Design and Failure Analysis of Radiant Section Lining in Cracking Furnace
Liu Man
2020, 32 (3):  42-45. 
Abstract ( 227 )  

This paper introduces the common structure of radiant section lining in cracking furnace in ethylene plant, the selection principle of heat insulation refractory material and the matters needing attention during the installation and construction of radiant section lining, and analyzes the reasons for the failure of radiant section lining,so as to improve the design scheme, minimize the premature damage of radiant section lining caused by design reasons and construction quality, improve the thermal efficiency of cracking furnace and prolong the service life of radiation section lining in cracking furnace.

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Research and Implementation of Energy Saving and Consumption Reduction Measures for Cracking Furnace in Ethylene Plant
Li Delong
2020, 32 (3):  46-49. 
Abstract ( 260 )  
With the rapid development of petrochemical enterprises in China, the competition among enterprises has become increasingly fierce, and energy saving, consumption reduction, cost reduction and efficiency improvement has become an inevitable trend of sustainable development for chemical plants. From the aspects of optimized COT control of cracking furnace, optimization of coke burning scheme, chemical cleaning of convection section, hydraulic coke cleaning of quench boiler and hole enlargement of dilution steam control valve of gas-phase furnace, the cracking furnace management was optimized to improve the operation efficiency of cracking furnace and reduce the energy consumption of ethylene plant.
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COMPRESSOR
Measures for Improving the Reliability of Compressor Oil Circuit System
Zhao Guicai
2020, 32 (3):  50-53. 
Abstract ( 205 )  

Oil circuit system is an important part of the compressor in ethylene plant, and the stable operation of oil circuit system directly affects the stable operation of ethylene plant. The reliability of oil circuit system can be improved from the aspects of preparation before commissioning, commissioning, routine operation and maintenance and design improvement. Strengthening the management on switching of oil coolers, oil filters and oil pumps, setting up a special maintenance team for critical compressor unit to ensure the daily maintenance, carrying out monthly sample analysis, checking the accumulator of oil circuit system on a regular basis (once every six months), following up the oil sample results, strengthening the inspection of oil circuit system and strengthening the maintenance of oil pump can ensure the stable operation of the oil circuit, thus ensuring the long period operation of ethylene plant.

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Study on Simulation and Application of Nitrogen Operation of Cracking Gas Compressor
Zhang Jianhua
2020, 32 (3):  54-56. 
Abstract ( 247 )  
The cracking gas compressor in the No.2 ethylene plant at PetroChina Daqing Petrochemical Company was not designed for nitrogen operation. Aspen Plus was used to build a nitrogen operation model for cracking gas compressor, and simulation was carried out by using the performance curve of the compressor to calculate the cooling capacity of CW cooler and the source of nitrogen during nitrogen operation. The nitrogen operation of cracking gas compressor was achieved for the first time, and the high pressure system was air sealed, so as to achieve the goal of zero leakage during the startup with real material.
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Online Treatment of Interstage Heat Exchanger Blockage of Cracking Gas Compressor
Wang Shengwei, Zhang Yingchun, Liu Yuanbo, Liu Jun, Wei Zheru
2020, 32 (3):  57-60. 
Abstract ( 339 )  

With the development of refining and petrochemical integration, ethylene plant is developing towards long term and high load operation, and the problems of compressor scaling and heat exchanger blockage becomes more prominent due to the lighter cracking feedstock. The effective control of compressor scaling and heat exchanger blockage is one of the key points to achieve the long-term operation of ethylene plant. The ethylene plant in Sichuan was restarted up after overhaul in June 2018, and the interstage heat exchanger in cracking gas compressor was blocked only one year later, seriously affecting the long-term operation of the ethylene plant. Based on cause analysis, some measures were taken including adding interstage dispersant, changing the composition of wash oil and installing the wash oil injection line of heat exchanger to achieve the expected effect, and the loss caused by the 10-day unplanned shutdown of ethylene plant each time was avoided.

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Cause Analysis and Solution to Abnormal Vibration of Turbine in Cracking Gas Compressor
Liu Xiaohui, Zhang Di, Liu Dong
2020, 32 (3):  61-64. 
Abstract ( 258 )  
During normal operation of the cracking gas compressor in the ethylene plant of PetroChina Liaoyang Petrochemical Company, abnormal vibration of turbine occurred many times, seriously affecting the safe operation of compressor unit. The factors influencing the process and equipment were investigated and analyzed comprehensively, the steam turbine was disassembled for repair, and the main factors causing the vibration of turbine were identified. The vibration of turbine was eliminated by taking corresponding treatment measures.
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Supervisor: China petrochemical corporation
Sponsor: China petrochemical engineering construction co. LTD
Address: 21 anhuili anyuan, chaoyang district, Beijing
Tel:010-84876209;84878482
E-mail:yxgy.sei@sinopec.com
ISSN:1671-7120
CN: 11-4819/TQ